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Er3+:Y0.5Gd0.5VO4晶体中Er3+离子的光谱特性

Spectral Properties of Y0.5Gd0.5VO4 Crystal Doped with Er3+ ion

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【作者】 黄晓辉游东宏李求忠

【Author】 HUANG Xiao-hui,YOU Dong-hong,LI Qiu-zhong(Department of Chemistry,Ningde Teachers College,Ningde,Fujian 352100,China)

【机构】 宁德师范高等专科学校化学系宁德师范高等专科学校化学系 福建宁德352100福建宁德352100

【摘要】 用提拉法(CZ法)生长出大尺寸、光学质量好的Er3+:Y0.5Gd0.5VO4单晶.在室温下,测量Er3+:Y0.5Gd0.5VO4晶体的吸收光谱、荧光光谱以及上转换荧光;利用Judd-Ofelt理论计算了Er3+离子在Y0.5Gd0.5VO4晶体中的振子强度P JJ′、自发辐射跃迁几率AJJ′和激发态荧光寿命τJ等光谱参数,在此基础上得出了Er3+:Y0.5Gd0.5VO4晶体的光学特性.

【Abstract】 Er3+:Y0.5Gd0.5VO4 single crystal with large size and good optical quality has been grown by Czochralski method.Its absorption and emission spectra were measured at room temperature.The absorption cross-sections are calculated on the basis of its spectra.According to Judd–Ofelt theory,the phenomenological intensity parameters ?λ of Er3+ ionshave been fitted adopting least-squares method.Moreover,the spectral parameters of Er3+ ions including oscillator strengths,radiative transition probabilities,radiative lifetimes and integrated emission cross-sections have been calculated.From the parameters mentioned above,the laser emission probability of Er3+:Y0.5Gd0.5VO4 crystal was discussed.

【基金】 福建省教育厅资助项目(JB06192);宁德师范高等专科学校校级资助项目(2006Y008)
  • 【文献出处】 漳州师范学院学报(自然科学版) ,Journal of Zhangzhou Normal University(Natural Science) , 编辑部邮箱 ,2007年03期
  • 【分类号】O734
  • 【被引频次】1
  • 【下载频次】62
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