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Depressing effect of phenoxyl acetic acids on flotation of minerals containing Ca2+/Mg2+ gangues

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【作者】 张剑锋胡岳华王淀佐徐竞

【Author】 ZHANG Jian-feng, HU Yue-hua, WANG Dian-zuo2, XU Jin (1. State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China; 2. School of Resources Processing and Bioengineering, Central South University, Changsha 410083, China)

【机构】 State Key Laboratory Base of Novel Functional Materials and Preparation Science Faculty of Materials Science and Chemical Engineering Ningbo UniversitySchool of Resources Processing and Bioengineering Central South UniversityNingbo 315211 China Changsha 410083 China Changsha 410083 China Changsha 410083 China

【摘要】 Phenoxyl acetic acids were applied to determine their depressing effect on minerals containing Ca2+/Mg2+ gangues. Calcite, mixture of calcite and fluorite, and nickel ore were used in the flotation. And the depression mechanism was studied by the determination of contact angle, zeta potential, adsorptive capacity of collector, and IR analysis as well. It is found that 0.1 mmol/L of phenoxyl acetic acid derived from pyrogallol or gallic acid exhibits strong depressing ability on calcite in almost zero yields at pH value of 9.8, and calcite can be depressed in the flotation of calcite/fluorite mixture for approximate 87% yield of fluorite. The flotation result of practical nickel ore containing serpentine indicates that these two depressants may also show better depression performance to serpentine than traditional depressants such as sodium fluosilicate and carboxylmethyl cellulose. Analysis for the depression mechanism reveals that there exists strong chemical interaction between the depressants and minerals.

【Abstract】 Phenoxyl acetic acids were applied to determine their depressing effect on minerals containing Ca2+/Mg2+ gangues. Calcite, mixture of calcite and fluorite, and nickel ore were used in the flotation. And the depression mechanism was studied by the determination of contact angle, zeta potential, adsorptive capacity of collector, and IR analysis as well. It is found that 0.1 mmol/L of phenoxyl acetic acid derived from pyrogallol or gallic acid exhibits strong depressing ability on calcite in almost zero yields at pH value of 9.8, and calcite can be depressed in the flotation of calcite/fluorite mixture for approximate 87% yield of fluorite. The flotation result of practical nickel ore containing serpentine indicates that these two depressants may also show better depression performance to serpentine than traditional depressants such as sodium fluosilicate and carboxylmethyl cellulose. Analysis for the depression mechanism reveals that there exists strong chemical interaction between the depressants and minerals.

【基金】 Project(Year 2005) supported by the Plan of High Learning Young Teacher of Zhejiang Province, China; Project(2005A620015) supported by the Ningbo Youth Science Fund, China;Project(2004745) supported by the Ningbo University for PhD
  • 【文献出处】 Journal of Central South University of Technology ,中南工业大学学报(英文版) , 编辑部邮箱 ,2007年06期
  • 【分类号】TD923
  • 【被引频次】3
  • 【下载频次】96
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