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聚酰胺6/热塑性聚氨酯共混物的流变性能
Rheological Behavior of PA6/TPU Blends
【摘要】 采用毛细管流变仪测试了聚酰胺6/热塑性聚氨酯(PA6/TPU)共混物的表观黏度、非牛顿指数等流变参数,讨论了剪切速率和温度对熔体表观黏度、剪切应力的影响。结果表明,PA6 和 PA6/TPU 共混物的表观黏度随着温度和剪切速率的增大而减小,非牛顿指数均小于1,符合假塑性流体的流动规律;PA6/TPU 共混物的表观黏度比PA6 的高,而其非牛顿指数比 PA6 的小,说明共混物的非牛顿性增强。在温度为230~250℃、剪切速率为100~1200s-1时,共混物的表观黏度为100~900 Pa·S,共混物适合挤出成型和注射成型。
【Abstract】 The rheological behavior of polyamide 6/thermoplastic polyurethane(PA6/TPU)blends was studied.The results showed that the apparent viscosity of PA6 and PA6/TPU blends decreased with increasing of the temperature and share rate.Non-Newtonian index is less than 1,which corresponds to pseudoplastic flow characteristics.The apparent viscosity of PA6/TPU blends is higher,non-Newtonian index is lower than that of PA6,respectively.In temperature range between 230℃ and 250℃,shear rate range between 100 s-1and 1200 s-1,the apparent viscosities of the blends were between 100 Pa·s and 900 Pa·s,which confirms that the blends are suitable for extrusion and injection molding.
【Key words】 polyamide 6; thermoplastic polyurethane; rheological behavior; blend;
- 【文献出处】 中国塑料 ,China Plastics , 编辑部邮箱 ,2007年11期
- 【分类号】TQ320
- 【被引频次】5
- 【下载频次】297