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海拉尔盆地乌尔逊凹陷片钠铝石的碳氧同位素组成及流体来源探讨

C-O isotope composition of dawsonite and its implication on the fluid origin in Wuerxun sag,Hailaer basin,China

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【作者】 高玉巧刘立张福松张延洁

【Author】 GAO YuQiao LIU Li ZHANG FuSong ZHANG YanJie College of Earth Sciences,Jilin University,Changchun 130061,China Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing 100029,China Center for Testing and Scientifw Experiment,Jilin University Changchun 130061,China

【机构】 吉林大学地球科学学院中国科学院地质与地球物理所吉林大学测试科学实验中心 长春 130061长春 130061北京 100029长春 130026

【摘要】 作为胶结物或交代自生矿物,片钠铝石(分子式为NaAlCO3(OH)2)大量发育于海拉尔盆地乌尔逊凹陷下白垩统南屯组、大磨拐河组砂岩中。根据片钠铝石稳定同位素组成,探讨了片钠铝石中碳的来源。片钠铝石的δ13C分布连续,其范围为-5.253‰~-1.210‰(PDB),δ18O分布范围为-24.896‰~-20.960‰(PDB),考虑到海拉尔盆地探井中未钻遇碳酸盐地层,片钠铝石属岩浆成因碳酸盐范畴。结合与片钠铝石平衡的CO2的δ13C值,含片钠铝石井和幔源CO2气井分布相吻合且位于燕山期花岗岩或附近的深大断裂带上,认为海拉尔盆地乌尔逊凹陷岩浆活动-砂岩成岩(片钠铝石形成)-幔源CO2气成藏不论在物质成分上还是在时空上均具备较好的耦合关系,形成片钠铝石所需的CO2气为与燕山期岩浆作用有关的幔源CO2气,深大断裂是深部CO2气向上运移到浅部砂岩的主要通道,片钠铝石形成时因油气充注而介入少量生物成因碳。

【Abstract】 Dasonite,NaAlCO3(OH)2,is widespread as a cement and replacement in sandstone from Nantun Formation and Damoguaihe Formation of the lower Cretaceous in Wuerxun sag,Hailaer basin.The origin of the carbon in dawsonite is studied by stable isotope composition.Dawsoniteδ13C(PDB)values range from-5.253‰to-1.210‰and are remarkably consistent.δ18O(PDB)values range from-24.896‰to-20.960‰.These values indicate magmatic source for carbon in the dawsonite in the view of the fact that carbonate rock is not available in all exploratory well in Hailaer basin.It can be concluded that the coupling between magma activity,diagenesis of sandstone(including the form of dasonite)and CO2 gas reservoir is fine either in composition or in space-time according to the calculatedδ13C values of CO2 gas in isotope equilibrium with dawsonite and the coincidence of dawsonite- containing well and CO2 gas well,lying along deep fracture within or adjacent to granite during Stage of Yanshan.Consequently, CO2 gas forming dawsonite is derived from mantle related to magmatic process during Stage of Yanshan.And deep fracture is main channel transporting CO2 gas from the deep to shallow sandstone.A little biologic origin carbon owing to petroleum charging intervened when dawsonite formed.

【基金】 国家自然科学基金项目:岩浆成因二氧化碳气藏中储集砂岩的热对流成岩作用(40372060)资助
  • 【文献出处】 岩石学报 ,Acta Petrologica Sinica , 编辑部邮箱 ,2007年04期
  • 【分类号】P597;P58
  • 【被引频次】15
  • 【下载频次】427
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