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BaWO4纳米线束的合成及其光学性质研究(英文)

Scheelite BaWO4 Nanowire Bundles:Controllable Synthesis and Optical Properties

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【作者】 张文莉韩敏关明云贺竞辉徐正

【Author】 ZHANG Wen-Li1,2 HAN Min1 GUAN Ming-Yun1 HE Jing-Hui1 XU Zheng,1 (1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093) (2School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013)

【机构】 南京大学化学化工学院 配位化学国家重点实验室南京大学化学化工学院配位化学国家重点实验室南京210093 江苏大学化学化工学院镇江212013南京210093

【摘要】 High quality BaWO4 nanowire bundles have been synthesized in toluene-sodium dodecylbenzene sulphonate (SDBS)-small amount PEG20000-H2O reverse micelle system. XRD result shows that the obtained BaWO4 belongs to tetragonal phase with scheelite structure. TEM results demonstrate that the obtained BaWO4 nanowire bundles have high aspect-ratio (>650). The experimental results confirm that PEG20000 plays a key role for the formation of BaWO4 nanowire bundles. Other factors which influence the morphology and crystallinity of the product are also briefly discussed. Moreover, the obtained BaWO4 nanowire bundles exhibit strong photoluminescence centered at 397.3 nm with λex=343.5 nm at room temperature, which is different from the bulk BaWO4 crystals.

【Abstract】 High quality BaWO4 nanowire bundles have been synthesized in toluene-sodium dodecylbenzene sulphonate (SDBS)-small amount PEG20000-H2O reverse micelle system. XRD result shows that the obtained BaWO4 belongs to tetragonal phase with scheelite structure. TEM results demonstrate that the obtained BaWO4 nanowire bundles have high aspect-ratio (>650). The experimental results confirm that PEG20000 plays a key role for the formation of BaWO4 nanowire bundles. Other factors which influence the morphology and crystallinity of the product are also briefly discussed. Moreover, the obtained BaWO4 nanowire bundles exhibit strong photoluminescence centered at 397.3 nm with λex=343.5 nm at room temperature, which is different from the bulk BaWO4 crystals.

【关键词】 BaWO4纳米线束反相胶束荧光
【Key words】 BaWO4nanowire bundlesreverse micellephotoluminescence
【基金】 国家自然科学基金资助项目(No.90606005,20490210)
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2007年10期
  • 【分类号】O614.233
  • 【被引频次】1
  • 【下载频次】151
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