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酚醛泡沫NaOH化学活化制备超级电容器用活性炭
THE PREPARATION OF THE ACTIVED CARBON FROM FENOLIC FOAM BY NaOH-ACTIVATION FOR ELECTRIC DOUBLE-LAYER CAPACITOR
【摘要】 以酚醛泡沫碎屑为原料,采用NaOH活化法制备比表面积为1750m2.-g 1的高比表面积活性炭,采用该材料作为电极材料,组装成超级电容器,并对它进行了恒电流充放电实验、循环伏安实验和交流阻抗等实验,结果表明,在炭化温度为800℃,碱炭比为2,活化温度为700℃时,制备的活性炭作电极材料组装的电容器的比容量达266.1F/g,具有良好的充放电性能和循环性能。
【Abstract】 The activated carbon with high specific surface area of 1 750m2·g-1was prepared from Fenolic Foam by NaOH-activation,which can be used as electrode materials for electric double-layer capacitor.Its electrochemical performance was determined by means of DC charge/discharge,cyclic voltammetry,and AC impedance analysis.Results showed that the specific capacitance of HSSAAC could reach 266.1 F/g by controlling suitable technology conditions:carbonization temperature was 700℃,ratio of NaOH to carbon was 2,activation temperature was 700℃.The EDLC with the activated carbon as electrode materials has good charge/discharge properties and recycle stability.
【Key words】 electric double-layer capacitor; high specific surface actived carbon; electrochemeical properties; Fenolic Foam; NaOH;
- 【文献出处】 炭素 ,Carbon , 编辑部邮箱 ,2007年04期
- 【分类号】TQ424.1
- 【被引频次】17
- 【下载频次】283