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新型混凝剂聚硅酸铁铝的制备及其混凝性能

PREPARATION OF A NEW COAGULANT PSAF AND ITS COAGULATION CAPABILITY

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【作者】 蔡忠胡翔米建英赵瑞军刘超

【Author】 CAI Zhong1,HU Xiang1,MI Jian-ying2,ZHAO Rui-jun3,LIU Chao4(1.College of Chemical Engineering,Beijing University of Chemical Technology,Beijing 100029,China; 2.State Administration of Work Safety,Beijing 100713,China;3.China National Offshore Oil Corp.,Beijing 100010,China; 4.Beijing Airsorb-Strong Environment Protection Science & Technology Co.Ltd,Beijing 100085,China)

【机构】 北京化工大学化学工程学院国家安全生产监督管理总局中国海洋石油总公司北京实创爱尔索环保科技有限公司 北京100029北京100029北京100713北京100010北京100085

【摘要】 聚硅酸铁铝(PSAF)是一种新型无机高分子混凝剂,因其高效的混凝性能,使用条件宽,药剂用量少,残留浓度低等而受到广泛关注。采用一步法用硅酸钠、硫酸铝(氯化铝)和硫酸铁(氯化铁)合成PSAF混凝剂,考察了不同制备条件对混凝剂混凝性能的影响,确定混凝剂的最佳制备工艺条件为:常温,(Fe+Al)/Si摩尔比为5:1,Fe/Al摩尔比为1:1,浓度(以硫酸盐计)为200 g/L。结果表明:此条件下合成的PSAF混凝剂性能优良,储存时间长。

【Abstract】 Polysilicate aluminum ferric(PSAF),a new inorganic polymer coagulant,has been extensively concerned,owing to its high-effective coagulation performance,wide applicable fields,less chemical dosage,low residual concentration,etc.PSAF was prepared through one-step synthesis by using Na2SiO3·9H2O,Al2(SO4)3(or AlCl3) and Fe2(SO4)3(or FeCl3);the influences of different conditions on the coagulation ability of PSAF were evaluated and the optimal preparation conditions were achieved as follows: ordinary temperature,the mole ratio of(Fe+Al) to Si was 5,the mole ratio of Fe to Al was 1,the mass concentration(based on sulfate) was 200 g/L.Experimental results indicated that the prepared PSAF under these conditions has excellent coagulation efficiency and relatively long storage period.

【基金】 教育部留学回国人员基金资助
  • 【文献出处】 水处理技术 ,Technology of Water Treatment , 编辑部邮箱 ,2007年11期
  • 【分类号】TU991.22
  • 【被引频次】18
  • 【下载频次】538
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