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聚中性红修饰电极测定维生素C的方法研究

Study on method of determining Vitamin C with poly(neutral red) modified electrode

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【作者】 张秋灵邹华常文贵

【Author】 ZHANG Qiu-ling1,ZOU Hua2,CHANG Wen-gui2(1 Hefei Railway Engineering School,Hefei 230011,Anhui,China;2 Department of Chemistry and Life Science,West Anhui University,Lu’an 237012,Anhui,China)

【机构】 合肥铁路工程学校皖西学院化学与生命科学系皖西学院化学与生命科学系 安徽合肥230011安徽六安237012

【摘要】 对聚中性红修饰电极的制备方法进行了研究,通过循环伏安法(CV)找到了制备电极的最佳实验条件。研究了VC在聚中性红修饰电极的电化学行为,发现聚中性修饰电极对VC有良好的伏安响应,在100mV/s的扫速下,VC在该修饰电极上产生一对准可逆氧化还原峰,峰电流与VC浓度在1.0×10-5~1.0×10-2mol/L范围内有良好的线性关系,检出限可达到1.0×10-6mol/L。与紫外光谱法作比较,该实验方法具有可行性。

【Abstract】 The preparation of poly(neutral red) modified electrod(PNRE) was studied,and the optimal experimental conditions for preparing the electrode were found by using the method of circlic voltammetry(CV).From the measurement of CV,it could be found that Vitamin C had a good voltammetric effect on PNRE and generated a pair of semi-reversible peaks of redox under the scanning velocity of 100mV/s.The intensity of peak electricity of Vitamin C was linear in the range of 1.0×10-5-1.0×10-2mol/L,and the detection limit was 1.0×10-6mol/L.In comparison with the ultraviolet spectrometry,the method mentioned above is feasible.

  • 【文献出处】 饮料工业 ,The Beverage Industry , 编辑部邮箱 ,2007年11期
  • 【分类号】O657.1
  • 【被引频次】16
  • 【下载频次】406
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