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微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)的水热自组装与晶体结构（英文）
Self-assembly and Crystal Structure of Microporous Fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H22N2) under Hydrothermal Conditions
【摘要】 采用水热合成法制备了一个三维微孔氟化磷酸镓Ga3P3O12F.0.5(1,8-C8H22N2)(简称Hit-6)。反应起始原料摩尔配比为:GaOOH:H3PO4:HF:1,8-辛二胺:H2O=1:2:1:1:555。Hit-6的骨架是由Ga3P3六聚体结构单元通过共顶点联接构成三维纳米孔结构,在[101]方向呈现8-元环孔道。
【Abstract】 A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H12N2) (named Hit-6) was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH:H3PO4:HF:1 8-diaminooctane:H2O=1:2:1:1:555. The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101] direction.
【关键词】 水热合成；
微孔；
氟化磷酸镓；
晶体结构；
【Key words】 hydrothermal synthesis； microporous； fluorogallophosphate； crystal structure；
【Key words】 hydrothermal synthesis； microporous； fluorogallophosphate； crystal structure；
【基金】 The project supported by the National Natural Science Foundation of China(No.20671025);Department of Education Foundationof Heilongjiang Province( No.10551335);the Natural Science Foundation of Heilongjiang Province ( No.13200603);Harbin Science and Technolongy Bureau Foundation of China(No.2005AFXXJ034)
- 【文献出处】 人工晶体学报 ,Journal of Synthetic Crystals , 编辑部邮箱 ,2007年05期
- 【分类号】O76
- 【下载频次】71