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神府煤制备磺化煤的研究及应用

STUDY AND APPLIED ON PREPARING SULFONATED COAL WITH SHENFU COAL

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【作者】 廖晓兰汪晓芹周安宁姚天国

【Author】 Liao Xiaolan Wang Xiaoqin and Zhou Anning and Yao Tianguo(Department of Materials Science and Engineering,Tianjin Institute of Urban Construction,300384 Tianjin; Department of Materials Engineering,Xi’an Universityof Science and Technology,710054 Xi’an;Department of EnergyTechnology and Mechnical Engineering,Tianjin Insititue ofUrban Construction,300384 Tianjin)

【机构】 天津城市建设学院材料科学与工程系西安科技大学材料工程系天津城市建设学院能源与机械工程系 300384天津硕士、讲师710054西安博士、副教授博士生导师、教授300384天津副教授

【摘要】 讨论了神府煤制备磺化煤的反应中,磺化温度、时间对煤磺化度和酸性基的影响,用FTIR对磺化煤进行结构表征,用体积溶胀法研究了磺化煤在苯胺中的溶胀特性.结果表明,煤的磺化度随着磺化温度的升高、磺化时间的延长而增大,煤经过磺化反应后其在苯胺中的溶胀性能也得到了改善.

【Abstract】 In the sulfonation reaction of coal,the effect of sulfonation temperature and time on the sulfonation value and acid groups of coal were researched,the structure of the sulfonated coal were identified by FTIR,the swelling property of sulfonated coal in aniline were studied by swelling.The result showed that the acidity of coal increased with the increase of temperature and time,the swelling property of coal in aniline were improved by the sulfonation reaction.

【关键词】 神府煤磺化反应溶胀
【Key words】 Shenfu coalsulfonation reactionswelling
【基金】 教育部科学技术研究重点项目(00232).
  • 【分类号】TQ536
  • 【被引频次】8
  • 【下载频次】276
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