【摘要】 合成了一种新型杂多酸荷移盐(C3N5H4NH3)3PW12O40,并用元素分析、红外光谱、紫外光谱对其进行表征.对该化合物的结构分析表明这些化合物中的多阴离子仍保留着其Keggin结构,但其特征振动谱带有一定的红移或蓝移.结果表明在配体和受体之间存在着很强的相互作用和电荷转移.形成电荷转移盐之后的杂多阴离子是一个独立的单元,它通过静电引力与C3N5H4NH3+作用,仍保持Keggin骨架结构.更多还原

【Abstract】 A novel compounds(C3N5H4NH3) 3PW12O40 has been synthesized and characterized by means of IR spectrum and UV spectrum.The structural analysis of precipitation has indicated that heteropoly anions in this compound still remained Keggin structure.However,the characteristic vibration bands have some red shift.The experiment results show that the donor and acceptor had very strong interactions and charge transfer.更多还原