【摘要】 在十六烷基三甲基溴化铵(CTAB)/正戊醇/异辛烷/水构成的油包水型(W/O)微乳体系中合成了膜状及50nm立方状的Co-Fe普鲁士蓝类配合物(cobalt-iron Prussian blue analogues).研究了w值(水与CTAB的物质的量的比)、反应物浓度和反应温度对产品形貌的影响.并用原子力显微镜(AFM),透射电子显微镜(TEM),电子能谱(EDS),X射线光电子能谱(XPS)和红外(IR)对产品进行了表征.更多还原

【Abstract】 Films and cubic nanoparticles with diameters of about 50 nm of cobalt-iron Prussian blue ana- logues (Co-Fe PBA) were synthesized in cetyl trimethyl ammonium bromide (CTAB)/n-pentanol/isooctane/ water reverse microemulsion. The effects of the water-to-surfactant molar ratio (w), the concentration of re- actants and the reaction temperature on the morphology of products were studied. The products were char- acterized by atomic force microscopy, transmission electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectroscopy and infrared spectroscopy.更多还原