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有机活性中间体氮烯的反应性及应用研究
Studies on Reactivity and Application of Organic Active Intermediate Nitrene
【摘要】 氮烯是合成含氮化合物的一类重要的有机活性中间体,具有反应活性高、反应类型多样等特点,在材料学、生命科学等高新科技领域中有着广泛的应用。主要介绍近年来从实验和理论计算方面研究氮烯双电子自由基的加成反应、插入反应、异构化反应等反应及应用。
【Abstract】 Nitrene is a very important kind of of ganic active intermediate to synthesize the compounds containing nitrogen,which has the characters of high reactivity,diversity of reaction type and so on.The recent developments of its.relevant reacions such as addition reaction,insertion reaction,and isomerization reaction etc were introduced.If could promote the further exploitation of nitrene and its applications in various fields of materialogy and life sciences etc.
【关键词】 氮烯;
有机合成;
活性中间体;
反应性;
应用;
【Key words】 nitrene organic synthesis active intermediate reactivity application;
【Key words】 nitrene organic synthesis active intermediate reactivity application;
【基金】 鲁东大学中青年自然科学基金(20062903);教学改革研究项目基金(Y0527、Y0715)资助;大学生科技创新基金(06B055、07L002)资助
- 【文献出处】 化工时刊 ,Chemical Industry Times , 编辑部邮箱 ,2007年10期
- 【分类号】O621.25
- 【下载频次】538