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PLS-BP法近红外光谱同时检测饲料组分的研究

Determination of Four Contents of Feedstuff Powder Using Near Infrared Spectroscopy by PLS-BP Model

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【作者】 刘波平秦华俊罗香曹树稳王俊德

【Author】 LIU Bo-ping1,2,QIN Hua-jun3,LUO Xiang2,4,CAO Shu-wen3,WANG Jun-de11.College of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China2.Analytical and Testing Center of Jiangxi Province,Nanchang 330029,China3.Key Laboratory of Food Science of MOE,Nanchang University,Nanchang 330047,China4.Department of Chemistry,Nanchang University,Nanchang 330047,China

【机构】 南京理工大学化工学院南昌大学食品科学教育部重点实验室江西省分析测试中心南京理工大学化工学院 南京江苏210094江西省分析测试中心南昌江西330029南昌江西3300474南昌江西330029南昌大学化学系南昌江西330047南京江苏210094

【摘要】 建立了用偏最小二乘(partial least squares,PLS)与人工神经网络(artificial neural networks,ANN)联用对饲料样品同时测定水分、灰分、蛋白质、磷含量的预测校正模型。光谱数据用二阶微分及标准归一化处理(SNV),用PLS法将原始数据压缩提取前10个主成分与2个特征峰值作为12个输入向量,采用单隐层的反向传播人工神经网络(Back-Propagation Network,BP),确定中间层的神经元个数为23,初始训练迭代次数为1000。PLS-BP模型对样品四个组分含量的预测决定系数(r2)分别为:0.9950,0.9980,0.9990和0.9670;样品平行扫描光谱预测值的标准偏差分别为:0.02774,0.04853,0.03292和0.02204。

【Abstract】 Partial least squares(PLS)and artificial neural networks(ANN)prediction model for four components of feedstuff has been established with good veracity and recurrence.The spectra put into the model should be processed by second derivative and standard normal variate(SNV).Ten principal components compressed from original data by PLS and two peak values were taken as the inputs of Back-Propagation Network(BP),while four predictive targets as outputs,according to Kolmogorov theorem and experiment,and twenty three nerve cells were taken as hidden nodes.Its training iteration times was supposed to be 10 000.Prediction deciding coefficient of four components by the model are 0.995 0,0.998 0,0.999 0 and 0.967 0,while the standard deviation of an unknown sample scanned parallelly are 0.027 74,0.048 53,0.032 92 and 0.022 04.

【基金】 教育部南昌大学食品科学重点实验室开放基金项目(NCU200404);江西省星火计划项目(2005年)资助
  • 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2007年10期
  • 【分类号】S816
  • 【被引频次】21
  • 【下载频次】307
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