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氯磺酸磺化PE非织薄膜及表征

Sulphuration and Characterization of PE Non-Woven Film by Chlorosulfonic Acid

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【作者】 孙元邓新华徐志成边栋材周晓峰

【Author】 SUN Yuan~(1,2),DENG Xin-hua~(1,2),XU Zhi-cheng~1,BIAN Dong-cai~(1,2),ZHOU Xiao-feng~(1,2)(1.School of Materials Science and Chemical Engineering,Tianjin Polytechnic University,Tianjin 300160,China;2.State Key Laboratory of Membrane Materials and Membrane Process of Ministry of Education,Tianjin Polytechnic University,Tianjin 300160,China)

【机构】 天津工业大学材料科学与化学工程学院天津工业大学材料科学与化学工程学院 天津300160天津工业大学国家教育部膜材料与膜过程重点实验室天津300160

【摘要】 通过磺化反应改善聚乙烯(PE)非织薄膜的亲水性,考察了时间、温度、物料配比等条件对磺化反应的影响,并用红外光谱(FT-IR)、X射线能量色散谱(EDS)及扫描电镜(SEM)对产物进行了表征,同时对PE非织薄膜的亲水性和力学性能进行了测定。结果表明:通过氯磺酸磺化可以将—SO3H基团引入PE大分子,磺化后的PE链段互相聚集无序堆砌形成微小颗粒;PE非织薄膜的断裂强度随磺化反应程度的增加而下降。

【Abstract】 The hydrophilic property of PE non-woven thin film was improved by using sulphuration.The effect of time,temperature and the ratio of reactants on the property of hydrophilic of PE were illustrated in detail.The introduction of —(SO3H) to sulphurated PE was characterized by(FT-IR) spectroscopy and energy dispersive X-ray(EDS).The result shows that not only the hydrophilic property of PE non-woven film is dramatically improved but also the original stretch intensity of PE non-woven film well retained when the sulphuration temperature is 80 ℃ and time is 1.5 h.

【基金】 天津市自然科学基金(013801811)
  • 【文献出处】 功能高分子学报 ,Journal of Functional Polymers , 编辑部邮箱 ,2007年03期
  • 【分类号】TQ320.721
  • 【被引频次】6
  • 【下载频次】294
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