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纳米BaAl2S4∶Eu2+发光材料的制备及性能
Preparation and Luminescence Characterizations of BaAl2S4∶Eu2+ Nanoparticles
【Abstract】 BaAl2S4∶Eu2+ nanoparticles with a size distribution of 50—150 nm were prepared by the sol-gel method. The particles were near spherical and had an intensive green emission when they were excited at 254 nm, after calcining at 1000 ℃ in a mixture of H2S(volume fraction 10%)+N2(volume fraction 90%) for 1.5 h. X-ray diffraction patterns indicate that BaAl2S4∶Eu2+ has a cubic structure. The emission and excitation spectra show that emission was from the 4f65d4f7 transition of the activated Eu2+. The highest photoluminescence(PL) luminance is 420 cd/m2. This study indicate that the BaAl2S4∶Eu2+ could be used as photoluminescent nanocomposite materials.
【关键词】 BaAl2S4∶Eu2+;
光致发光;
电致发光;
纳米粒子;
【Key words】 BaAl2S4∶Eu2+; Photoluminescence; Electroluminescence; Nanoparticle;
【Key words】 BaAl2S4∶Eu2+; Photoluminescence; Electroluminescence; Nanoparticle;
【基金】 国家自然科学基金(批准号:60374248)资助.
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2007年10期
- 【分类号】TB383.1
- 【下载频次】188