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纳米BaAl2S4∶Eu2+发光材料的制备及性能

Preparation and Luminescence Characterizations of BaAl2S4∶Eu2+ Nanoparticles

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【作者】 申连春于连香朱万春田玉美

【Author】 SHEN Lian-Chun, YU Lian-Xiang, ZHU Wan-Chun, TIAN Yu-Mei(College of Chemistry, Jilin University, Changchun 130012, China)

【机构】 吉林大学化学学院吉林大学化学学院 长春130012长春130012

【Abstract】 BaAl2S4∶Eu2+ nanoparticles with a size distribution of 50—150 nm were prepared by the sol-gel method. The particles were near spherical and had an intensive green emission when they were excited at 254 nm, after calcining at 1000 ℃ in a mixture of H2S(volume fraction 10%)+N2(volume fraction 90%) for 1.5 h. X-ray diffraction patterns indicate that BaAl2S4∶Eu2+ has a cubic structure. The emission and excitation spectra show that emission was from the 4f65d4f7 transition of the activated Eu2+. The highest photoluminescence(PL) luminance is 420 cd/m2. This study indicate that the BaAl2S4∶Eu2+ could be used as photoluminescent nanocomposite materials.

【基金】 国家自然科学基金(批准号:60374248)资助.
  • 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2007年10期
  • 【分类号】TB383.1
  • 【下载频次】188
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