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新型纳米TiO2自清洁氟碳涂料的性能研究

Photocatalytic Behavior and Self-Cleaning Function of Nano-TiO2 in Fluorocarbon Paint

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【作者】 杨景花余刚胡波年何耀华杨国良

【Author】 YANG Jing-hua1,YU Gang1,HU Bo-nian1,HE Yao-hua2,YANG Guo-liang2(1.College of Chemistry and Chemical Engineering,Hunan University,Changsha 510082,China;2.Hunan Huatian Aluminum Co.Ltd.,Changsha 410100,China)

【机构】 湖南大学化学化工学院湖南华天铝业有限公司湖南华天铝业有限公司 湖南长沙410082湖南长沙410082湖南长沙410100

【摘要】 研究了纳米TiO2在涂料中的光催化性能,及其使氟碳涂料(PVDF)产生的自清洁作用。从物理机械分散和表面改性两个方面,分别讨论了纳米TiO2在氟碳涂料中分散性的影响因素。结果表明,加入371A、Tween-80及Tritonx-100等分散剂,以转速6000r/min机械分散45min,超声分散60min,可以提高纳米TiO2在氟碳涂料中的分散性,且纳米TiO2在氟碳涂料中具有优良的自清洁作用。

【Abstract】 The photocatalysis and self-cleaning function of nano-titanium dioxide(nano-TiO2)in fluorocarbon paint(PVDF)were investigated.The factors affecting the dispersion behavior of the nano-TiO2 in the PVDF were analyzed with respect to mechanical dispersion and surface modification.It was found that nano-TiO2 had an average diameter of less than 100 nm and could be dosed into the fluorocarbon paint up to a mass fraction of 2%~3%.The dispersion of nano-TiO2 in the fluorocarbon paint could be improved when mechanically dispersed at a rate of 6 000 r/min for 45 min or ultrasonically dispersed for 60 min in the presence of 371 A,Tween-80 and Tritonx-100 as the dispersants.Moreover,nano-TiO2 had good self-cleaning function in the fluorocarbon paint.

【基金】 湖南省建设厅2003年科研基金资助(897214003)
  • 【文献出处】 材料保护 ,Materials Protection , 编辑部邮箱 ,2007年06期
  • 【分类号】TB383.1
  • 【被引频次】18
  • 【下载频次】804
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