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PBT/PA610共混合金的制备及其力学性能的研究

STUDY ON PREPARATION AND MECHANICAL PROPERTIES OF PBT/PA610 BLEND ALLOYS

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【作者】 胡雪梅王玉东刘民英郭方方霍丽林浩伟赵清香

【Author】 Hu Xuemei1,Wang Yudong1,2,Liu Minying1,Guo Fangfang1,Huo Li1,Lin Haowei1,Zhao Qingxiang1(1.School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450052,China;2.Pingdingshan Shenma Engneering Plastics Co.Ltd.,Pingdingshan 467013,China)

【机构】 郑州大学材料科学与工程学院郑州大学材料科学与工程学院 郑州450052郑州450052 平顶山神马工程塑料有限责任公司平顶山467013郑州450052

【摘要】 选用环氧树脂(EP)、(苯乙烯/乙烯-丁烯/苯乙烯)三嵌段共聚物接枝马来酸酐(SEBS-g-MAH)和(乙烯/马来酸酐/甲基丙烯酸缩水甘油酯)三元共聚物(EMG)为增容剂,采用熔融挤出的方法制备了PBT/PA610/EP、PBT/PA610/EP/SEBS、PBT/PA610/EP/EMG3种合金,研究了这3种合金的力学性能。结果表明,当PBT/PA610/EP的质量比为70/30/3时,合金的冲击强度比不加EP时提高了37.3%,比纯PBT提高了91.2%;而且在PBT/PA610/EP的质量比为70/30/3时,随着SEBS-g-MAH和EMG含量的增加,合金的冲击强度也明显提高。

【Abstract】 Poly(buty1ene terephthalate)(PBT) /polyamide 610(PA610) blends compatibilized with epoxy resin(bisphenol type-A),SEBS-g-MAH(a ternary copolymer of high molecular weight styrene,butadiene) and EMG(a ternary copolymer of high molecular weight polyethylene,maleic anhydride and glycidyl methacrylate) were prepared by extrusion followed by injection molding.The mechanical properties of the prepared alloys were studied.The results showed that the notched lzod impact strength was 137.3% higher than that of alloy without epoxy resin and was 191.2% higher than that of pure PBT;when the ratio of PBT/PA610/EP was 70/30/3,the notched lzod impact strength increased obviously with the increase of SEBS-g-MAH or EMG content.

【关键词】 PBTPA610环氧树脂SEBS-g-MAHEMG
【Key words】 PBTnylon 610epoxy resinSEBS-g-MAHEMG
【基金】 河南省杰出人才创新基金项目(0521001300)
  • 【文献出处】 工程塑料应用 ,Engineering Plastics Application , 编辑部邮箱 ,2007年10期
  • 【分类号】TQ327
  • 【被引频次】14
  • 【下载频次】381
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