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稀土元素镱在ZK31镁合金中的分布
Distribution of Rare Earth Element Yb in the Magnesium Alloy ZK31
【摘要】 研究了ZK31+xYb合金中Yb的分布及作用。结果表明:Zn和Yb能相互降低对方在镁合金中的溶解度,少量(1 0%)的Yb加入ZK31合金中,Zn与Yb的分布都较均匀,在凝固过程中优先形成Yb Zn金属间化合物,提高Yb含量(2 0%),Yb向晶界偏聚,并促使Zn向晶界偏聚,凝固过程中有少量金属间化合物Mg2Zn2Yb先于α Mg形成,大部分的Yb和Zn在凝固后期形成金属间化合物Mg15Zn2Yb,进一步提高Yb的含量,固溶以外的Yb和Zn均向晶界偏聚,在凝固后期形成金属间化合物Mg15Zn2Yb和Mg10Zn3Yb2。此外,Yb元素能有效细化ZK31镁合金的晶粒。
【Abstract】 The distribution and role of Yb in the magnesium alloy ZK31+xYb were studied.The result shows: Zn and Yb can decrease the solubility in magnesium each other.With small quantity addition of Yb(1.0%),both Zn and Yb distribute homogenously in the ZK31 magnesium alloy,and Yb-Zn binary intermetallics formed prior to α-Mg during solidification.Increasing of Yb addition,Yb began to segregate to grain boundary,and it can promote the segregation of Zn,a small amount of Mg-Zn-Yb ternary intermetallics Mg2Zn2Yb formed prior to α-Mg during solidification,but most of the Yb and Zn formed ternary intermetallics Mg15Zn2Yb in the lateral stage of solidification.With further increasing of Yb addition,most of the Yb and Zn segregated to the grain boundary to form ternary intermetallics Mg15Zn2Yb and Mg10Zn3Yb2 except the soluted ones.Moreover,Yb can obviously refine the grain of magnesium alloy ZK31.
【Key words】 magnesium alloy; Yb; intermetallics; segregation; grain refinement;
- 【文献出处】 铸造 ,Foundry , 编辑部邮箱 ,2005年04期
- 【分类号】TG115
- 【被引频次】10
- 【下载频次】208