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淬速对Ni-Mn-Ga快淬合金相变的影响
Effect of quenching rate on phase transformation of Ni-Mn-Ga melt-spinning alloys
【摘要】 采用快淬技术制备了Ni-Mn-Ga薄带合金,研究了不同淬速对Ni-Mn-Ga快淬合金相变过程的影响。结果表明,快淬合金具有典型的热弹性马氏体相变过程,但合金的马氏体相变开始温度Ms比铸态合金的有所降低,并随淬速的升高,快淬合金的Ms逐渐降低。Ni-Mn-Ga合金马氏体相变的热力学分析表明:快淬合金晶粒愈细小,Ms愈低;快淬工艺不改变合金的晶体结构;在不同淬速的快淬合金中有以(400)晶面为择优取向的织构存在。
【Abstract】 Ni-Mn-Ga ribbons were prepared by melt-spinning technology.The effects of quenching rates on phase transformation of Ni-Mn-Ga melt-spinning alloy were investigated.The results show that Ni47Mn32Ga21 melt-spun ribbons undergo typical thermal-elastic martensitic transformation and magnetic transition.However,Ms of melt-spun ribbons is lower than that of as-cast alloy and decreases with increasing quenching rate.Based on transformation thermodynamics analysis,the smaller the grain sizes of melt-spun alloys are,the lower the Ms is.The melt-spinning technology does not change the crystal structure of the alloy.There exist obvious textures with(400) crystal plane preferential oriented crystal structure in the melt-spun alloys with different quenching rates.
【Key words】 Ni-Mn-Ga; magnetic shape memory alloy; martensitic transformation; melt-spinning;
- 【文献出处】 中国有色金属学报 ,The Chinese Journal of Nonferrous Metals , 编辑部邮箱 ,2005年11期
- 【分类号】TG156.3
- 【被引频次】12
- 【下载频次】157