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Effect of nucleating agents on microstructure and mechanical properties of SiO2-Al2O3-ZrO2 glass-ceramics

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【作者】 余丽萍肖汉宁胡鹏飞

【Author】 YU Li-ping 1,2, XIAO Han-ning1, HU Peng-fei1(1. School of Materials Science and Engineering, Hunan University, Changsha 410082, China; 2. School of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China)

【机构】 School of Materials Science and Engineering Hunan University Changsha 410082 ChinaSchool of Chemistry and Chemical Engineering Hunan Normal University Changsha 410081 ChinaSchool of Materials Science and Engineering Hunan University Changsha 410082 China

【Abstract】 SiO2-Al2O3-ZrO2 glasses with different nucleating agents were crystallized under special processing schedule. The microstructure and mechanical properties of the glass-ceramics in SiO2-Al2O3-ZrO2 system were investigated by differential scanning calorimetry, scanning electron microscopy, X-ray diffraction and three-point bending method. The results show that ZrO2 is not an effective nucleating agent in SiO2-Al2O3-ZrO2 system, while TiO2 is effective for the separation of spinel, and P2O5 facilitates solubility of ZrO2 in glass and crystallization. The main crystalline phases of the glass-ceramics are spinel, anorthite and tetragonal zirconia. With the increase of ZrO2 content in the glass, glass-ceramics show higher bending strength (120MPa) than others.

【基金】 Project(2003AA332040)supportedbytheNationalHighTechnologyResearchandDevelopmentProgramofChina
  • 【文献出处】 Journal of Central South University of Technology(English Edition) ,中南工业大学学报(英文版) , 编辑部邮箱 ,2005年05期
  • 【分类号】TQ174
  • 【被引频次】2
  • 【下载频次】43
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