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Synergistic Effect of Amphiphiles at Oil-Water Interface: By Monte Carlo Simulation

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【作者】 潘海华李浩然韩世钧

【Author】 PAN Haihua, LI Haoran and HAN Shijun Department of Chemistry, Zhejiang University, Hangzhou 310027, China

【机构】 Department of ChemistryZhejiang UniversityHangzhou 310027ChinaChina

【摘要】 <正>Amphiphile-oil-water system is complicated. The real behavior of amphiphile in the interface is still undnown despite that this behavior is very important in determining the stability of emulsion system. In this paper, the interface properties of amphiphile at oil-water interface were investigated by a square-lattice model Monte Carlo simulation method. The synergistic effect was found for hydrophobic and hydrophilic amphiphile mixture systems; and the synergistic effect disappears or was weakened as the amphiphile at the interface region became dilute with the increasing of temperature.

【Abstract】 Amphiphile-oil-water system is complicated. The real behavior of amphiphile in the interface is still undnown despite that this behavior is very important in determining the stability of emulsion system. In this paper, the interface properties of amphiphile at oil-water interface were investigated by a square-lattice model Monte Carlo simulation method. The synergistic effect was found for hydrophobic and hydrophilic amphiphile mixture systems; and the synergistic effect disappears or was weakened as the amphiphile at the interface region became dilute with the increasing of temperature.

【基金】 Supported by the National Natural Science Foundation of China (No. 29736170) the Natural Science Foundation of Zhejiang Province (No. RC01051).
  • 【文献出处】 Chinese Journal of Chemical Engineering ,中国化学工程学报(英文版) , 编辑部邮箱 ,2005年03期
  • 【分类号】O648.23
  • 【下载频次】59
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