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溶液共混法制备高强度淀粉基完全生物降解塑料薄膜
Fully Biodegradable Starch Based Film with High Strength Prepared by Solution Mixing Method
【摘要】 利用一步溶液共混法,将预糊化的淀粉糊与PVA溶液共混,用乙二醛进行交联,制备淀粉/聚乙烯醇(PVA) 完全生物降解塑料薄膜。研究不同乙二醛和甘油的用量对薄膜性能的影响。薄膜的力学性能、热性能和微观形态表征表明,淀粉/PVA体系具有较好的相容性和较高的力学性能,薄膜的拉伸强度和断裂伸长率分别可达到28.52 MPa 和307.5%。
【Abstract】 Fully biodegradable film of starch/poly(vinyl alcohol) was prepared via one-step solution mixing method, in which glyoxal was introduced directly into the mixture of pregelatinized starch paste and poly (vinyl alcohol) solution as a crosslinker. The effect of volume fraction of glyoxal and glycerin on plastic film’s properties was studied. The starch/poly (vinyl alcohol) blend possessed better compatibility and higher mechanical properties. The film’s tensile strength and elongation at break was 28. 52 MPa and 307.5 %, respectively.
【关键词】 淀粉;
聚乙烯醇;
生物降解;
溶液共混;
【Key words】 starch; poly(vinyl alcohol); biodegradation; solution mixture;
【Key words】 starch; poly(vinyl alcohol); biodegradation; solution mixture;
【基金】 沈阳市科学技术计划项目(1032040-1-03);沈阳化工学院博士启动基金项目资助(200202)
- 【文献出处】 中国塑料 ,China Plastics , 编辑部邮箱 ,2005年11期
- 【分类号】TQ320.721
- 【被引频次】6
- 【下载频次】401