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β晶型等规聚丙烯/EPDM体系的结晶和力学性能的研究
Mechanical Properties and Melting Crystallization Behavior of β-form Polypropylene/EPDM Blends
【摘要】 研究了β晶型聚丙烯/三元乙丙橡胶(EPDM)的力学性能,通过广角X射线衍射和偏光显微镜对聚丙烯的晶型进行了表征。结果表明:β晶型聚丙烯/EPDM具有较高的冲击强度,与未经β晶成核剂处理的PP/EPDM相比,冲击强度提高1~2倍,聚丙烯β晶增韧和EPDM增韧具有加和效应;β晶型聚丙烯/EPDM的拉伸强度稍低于未经β晶成核剂处理的PP/EPDM;β晶型聚丙烯与α晶相比,球晶尺寸显著降低,晶界模糊,EPDM在其中分散更为均匀。
【Abstract】 The polypropylene/EPDM blends were studied using WAXD and PLM. It was found that the Izod notched impact strength based on β-form PP was 1~2 times higher than that based on α-form, however, the tensile strength was somewhat lower. The β-form crystallites were smaller than that of α-ones and possessed more smeared boundary between the spherulites. EPDM was more finely dispersed in β-form PP than in α-form.
【关键词】 聚丙烯;
β晶;
三元乙丙橡胶;
增韧;
【Key words】 polypropylene; β-form crystal; ethylene propylene terpolymer rubber; toughening;
【Key words】 polypropylene; β-form crystal; ethylene propylene terpolymer rubber; toughening;
【基金】 国家高新技术研究发展863计划(2003AA324010)
- 【文献出处】 中国塑料 ,China Plastics , 编辑部邮箱 ,2005年06期
- 【分类号】TQ325.14
- 【被引频次】8
- 【下载频次】296