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新型含磷双酚A型共聚碳酸酯的合成与表征
Synthesis and Characterization of a Phosphorus-containing Polycarbonate with Bisphenol-A Moiety
【Abstract】 A novel phosphorus-containing copolycarbonate was synthesized from bisphenol-A,2-(6-oxido-6H-dibenz<c,e><1,2>oxa phosphorin-6-yl)-1,4-dihydroxy phenylene(ODOP-HQ) and triphosgene by interfacial polycondensation,and a copolycarbonate with an inherent viscosity of 0.53 dL/g was obtained.The(copolymer) was characterized by elemental analysis,FT-IR,DSC,TGA,and NMR.DSC result shows that the Tg of the copolycarbonate is 149 ℃,which is higher than that of normal PC.The TGA(result) shows that the onset decomposition temperature of the copolycarbonate is 355 ℃,which indicates it(possesses) a good thermal stability.
【基金】 国家自然科学基金资助项目(50203008)
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2005年12期
- 【分类号】TQ323.4
- 【被引频次】7
- 【下载频次】249