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真空碳热还原氧化镁的热力学分析及实验验证

Thermodynamical Analysis and Experimental Test of Magnesia Vacuum Carbothermic Reduction

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【作者】 李志华戴永年薛怀生

【Author】 LI Zhi-hua, DAI Yong-nian, XUE Huai-sheng (Faculty of Material and Metallurgy Engineering, Kunming University of Science and Technology, Kunming 650093, China)

【机构】 昆明理工大学材料与冶金工程学院昆明理工大学材料与冶金工程学院 昆明650093昆明650093昆明650093

【摘要】 对真空条件下用碳还原氧化镁反应进行热力学分析,计算出不同条件下C还原MgO所需要的最低反应温度及相应的露点温度。结果表明,真空下用碳还原氧化镁得到液态冷凝镁的还原温度不应低于13 5 2℃,对应的露点温度在65 1℃以上。用自制的真空碳热炼镁小型真空炉,验证试验得到了块状的冷凝金属镁

【Abstract】 The magnesia reducing reaction with carbon as reductant in vacuum condition is thermodynamically analyzed and the minimum temperature required for the reduction under various conditions and corresponding dew-point temperature are calculated. It is indicated by the calculation result that the reduction temperature should be over 1352℃, therefore the corresponding dew-point temperature is higher than 651℃. The fringe crystal of magnesium is obtained by the confirmation experiments in a small scale vacuum furnace made for magnesia reduction.

【基金】 云南省自然科学基金资助项目 (2 0 0 0E0 0 2 6M )
  • 【分类号】TF822
  • 【被引频次】41
  • 【下载频次】508
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