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Ru,CeO2,MnO2/TiO2新型CWO催化剂的研制

The study of preparation Ru-CeO2-MnO2/TiO2 catalystfor catalytic wet air oxidation process

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【作者】 李自弘涂学炎杨中民张世鸿金胜白云沈富昆

【Author】 LI Zi-hong, TU Xue-yan, YANG Zhong-mim, ZHANG Shi-hong, JIN Sheng, BAI Yun, SHEN Fu-kun(Collge of Chemistry and Material Engineering,Yunnan University,Kunming 650091,China)

【机构】 云南大学化学与材料工程学院化学系云南大学化学与材料工程学院化学系 云南昆明 650091云南昆明 650091云南昆明 650091

【摘要】 制备了载体为TiO2,活性组分为Ru(w=0.5%)和Ce,Mn的氧化物的催化湿式氧化法催化剂.制备中运用了Ce,Mn硝酸盐对载体的浸渍法预处理和表面纳米化技术的组合.研究了对模拟废水的催化湿式氧化分解的催化活性,COD去除率近70%,NH3-N去除率87.9%.

【Abstract】 The study of preparation of Ru-CeO2-MnO2/TiO2 catalyst for catalytic wet air oxidation process the catalyst in which active components were Ru(0.5%),Ce and Mn oxides supported on TiO2 was prepared with technique of surface nanometerizing.The catalyst has been applied in catalytic wet air oxidation (CWO) process of simulated wastewater containing succinic acid and (NH42SO4.It was found that its catalytic activity was acceptable by the dterminations of COD and TN of the simulated wastewater.The ratio of removing COD was about 70%,and vatio of removing NH3-N was 87.9%.

【基金】 云南省"十五"攻关资助项目(2001GG18).
  • 【文献出处】 云南大学学报(自然科学版) ,Journal of Yunnan University (Natural Sciences) , 编辑部邮箱 ,2005年02期
  • 【分类号】X703.5
  • 【被引频次】5
  • 【下载频次】215
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