【摘要】 研究了八乙基卟啉钌(II)及四种带有不同取代基的四苯基卟啉羰基合钌(II)的电化学行为,考察了取代基对羰基钌卟啉的电化学性质的影响,测定了其电子转移反应速率常数。更多还原

【Abstract】 The redox properties of four para-substituted tetraphenylporphyrin carbonyl complexes of ruthenium(II) and carbonyl octakisethyl-porphyrinatoruthenium(II) have been investigated using electrochemical techniques.The standard rate constants of electron transfer of the five compounds have been obtained and the effects of substituents on the electrode reactions of the five porphyrin carbonyl complexes of ruthenium(II) have been disccussed.更多还原