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P+Sr+Ce复合变质对高硅耐热铝合金组织与性能的影响

Effect of P+Sr+Ce Compound Modification on Microstructure and Properties of Cast High Silicon Heat-Resist Aluminum Alloy

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【作者】 赵品逯允海

【Author】 Zhao Pin~*, Lu Yunhai (Key Laboratory of Metastable Materials Science & Technology, Yanshan University, Qinhuangdao 066004, China)

【机构】 燕山大学材料学院河北省亚稳材料制备技术与科学重点实验室燕山大学材料学院河北省亚稳材料制备技术与科学重点实验室 河北秦皇岛066004河北秦皇岛066004

【摘要】 采用正交实验设计方法研究了Al-21Si-1.5Cu-1.5Ni-2.5Fe-0.5Mg合金P+Sr+Ce复合变质。正交实验表明变质剂的最佳加入量(质量分数)为:2%(CaH2PO4+2CaSO4)+0.2%Sr+0.2%Ce,可一次细化初晶硅与共晶硅,并改善富铁相形态。X射线衍射分析与能谱分析表明,未变质合金中的针状富铁相为Al9FeSi3,复合变质使粗大针状富铁相消失,生成鱼骨状富铈富铁相Al8CeFe4。在最佳变质条件下,室温抗拉强度与300℃瞬时抗拉强度均比未变质合金提高约30%,扫描电镜观察发现拉伸断口由脆性的沿晶断裂变为混合断口,断口中有大量韧窝存在。

【Abstract】 The P+Sr+Ce compound modification technologies of as-cast Al-21Si-1.5Cu-1.5Ni- 2.5Fe-0.5Mg alloy were investigated by means of orthogonal test. Orthogonal test results show that 2% (CaH2PO4+2CaSO4)+0.2%Sr+0.2%Ce is the optimum additive of modification treatment which can fine eutectic and primary silicon also can change the form of rich-iron phase at same time. The needle form of rich-iron phase is (Al9FeSi3), which is proved by X-ray diffraction analysis and X-ray energy spectrum analysis. After compound modification treatment, the needle form of rich-iron phase disappeared and the fish bone form of rich-iron and rich-Ce phase that is Al8CeFe emerged. Both at room temperature and at 300 ℃, the tensile strength of the alloy after the modification treatment with the optimum additive is 30% lager than that of the alloy unmodified. Observed by SEM, the brittle intercrystalline tensile fracture changed into a blended one in which has many dimples.

  • 【文献出处】 中国稀土学报 ,Journal of The Chinese Rare Earth Society , 编辑部邮箱 ,2005年04期
  • 【分类号】TG113
  • 【被引频次】23
  • 【下载频次】230
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