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P+Sr+Ce复合变质对高硅耐热铝合金组织与性能的影响
Effect of P+Sr+Ce Compound Modification on Microstructure and Properties of Cast High Silicon Heat-Resist Aluminum Alloy
【摘要】 采用正交实验设计方法研究了Al-21Si-1.5Cu-1.5Ni-2.5Fe-0.5Mg合金P+Sr+Ce复合变质。正交实验表明变质剂的最佳加入量(质量分数)为:2%(CaH2PO4+2CaSO4)+0.2%Sr+0.2%Ce,可一次细化初晶硅与共晶硅,并改善富铁相形态。X射线衍射分析与能谱分析表明,未变质合金中的针状富铁相为Al9FeSi3,复合变质使粗大针状富铁相消失,生成鱼骨状富铈富铁相Al8CeFe4。在最佳变质条件下,室温抗拉强度与300℃瞬时抗拉强度均比未变质合金提高约30%,扫描电镜观察发现拉伸断口由脆性的沿晶断裂变为混合断口,断口中有大量韧窝存在。
【Abstract】 The P+Sr+Ce compound modification technologies of as-cast Al-21Si-1.5Cu-1.5Ni- 2.5Fe-0.5Mg alloy were investigated by means of orthogonal test. Orthogonal test results show that 2% (CaH2PO4+2CaSO4)+0.2%Sr+0.2%Ce is the optimum additive of modification treatment which can fine eutectic and primary silicon also can change the form of rich-iron phase at same time. The needle form of rich-iron phase is (Al9FeSi3), which is proved by X-ray diffraction analysis and X-ray energy spectrum analysis. After compound modification treatment, the needle form of rich-iron phase disappeared and the fish bone form of rich-iron and rich-Ce phase that is Al8CeFe emerged. Both at room temperature and at 300 ℃, the tensile strength of the alloy after the modification treatment with the optimum additive is 30% lager than that of the alloy unmodified. Observed by SEM, the brittle intercrystalline tensile fracture changed into a blended one in which has many dimples.
【Key words】 high silicon aluminum alloy; compound modification; orthogonal test; mechanical property; rare earths;
- 【文献出处】 中国稀土学报 ,Journal of The Chinese Rare Earth Society , 编辑部邮箱 ,2005年04期
- 【分类号】TG113
- 【被引频次】23
- 【下载频次】230