节点文献
固-液相转移催化法合成N-芳酰基-N-′(4-芳氧基苯基)硫脲衍生物
Synthesis of N-aroyl-N′-(4-aryloxyphenyl)thiourea derivatives under the condition of phase transfer catalysis
【摘要】 在固液相转移催化条件下,以PEG-400为催化剂,通过芳酰氯与硫氰酸铵反应合成了中间体芳酰基异硫氰酸酯;后者不需分离,直接与芳胺反应,高产率获得N-芳酰基-N′-(4-芳氧基苯基)硫脲衍生物.
【Abstract】 Aroyl isothiocyanate is synthesized by the reaction of aroyl chloride with ammonium thiocyanate under the condition of solidliquid phase transfer catalysis using PEG400 as the catalyst.The later need not to be isolated and reaction with aromatic amine immediately to give NarylN′(4aryloxyphenyl)thiourea derivatives in high yield.The promoting effects of the title compounds on wheat growth are tested preliminary.
【关键词】 N-芳酰基-N-′(4-芳氧基苯基)硫脲衍生物;
相转移催化;
生物活性;
【Key words】 N-aryl-N′-(4-aryloxypheny)thiourea derivatives; phase transfer catalysis; biological activity;
【Key words】 N-aryl-N′-(4-aryloxypheny)thiourea derivatives; phase transfer catalysis; biological activity;
【基金】 国家自然科学基金资助项目(20371040);甘肃省自然科学基金资助项目(031-A21-004);西北师范大学青年基金资助项目(02-08)
- 【文献出处】 西北师范大学学报(自然科学版) ,Journal of Northwest Normal University(Natural Science Edition) , 编辑部邮箱 ,2005年04期
- 【分类号】TQ450.1;
- 【被引频次】7
- 【下载频次】158