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氧化铝胶体的添加对氧化铝γ→α相变的影响
Effect of Addition of Alumina Sol on γ→α Phase Transformation of Ultrafined Alumina
【摘要】 在γ-Al2O3粉体中添加氧化铝胶体,研究其对氧化铝α相变的影响.结果表明,与α氧化铝粉体籽晶相比较,氧化铝胶体也可以起到籽晶的作用;由于其颗粒较小、在γ-Al2O3中分散均匀且能与之紧密接触,大大降低了α相变温度,改善了煅烧产物的微结构,从而得到分散均匀、平均粒径<100nm 的α氧化铝超细粉体,根据对粉体形貌 TEM 的观察,初步探讨了添加氧化铝胶体的前驱体α相变的过程。
【Abstract】 The effect of alumina sol on the α phase transformation in γ-alumina powder has been studied.Incomparison with α-alumina seeds,the alumina sol can also act as seeds.Moreover,because of the small particlesize and perfect dispersibility of the alumina sol,the α phase transformation temperature is decreased and,meanwhile,the microstructure of the produced powders is modified.So ultrafined powders with a particle sizeless than 100 nm were produced with good dispersibility.The α phase transformation of the alumina precursorswith alumina sol doping was studied on the base of the TEM photographs of the produced powders.
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,2005年01期
- 【分类号】TB383
- 【被引频次】25
- 【下载频次】580