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氧化铝胶体的添加对氧化铝γ→α相变的影响

Effect of Addition of Alumina Sol on γ→α Phase Transformation of Ultrafined Alumina

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【作者】 吴玉程杨晔李勇崔平

【Author】 WU,Yu-Cheng~(1,2) YANG,Ye~2 LI,Yong~2 CUI,Ping~2~1Faculty of Materials Science & Engineering,Hefei University of Technology,Hefei 230009;~2Nano Science & Technology Center,Institute of Solid State Physics Chinese Academy of Sciences,Hefei 230031

【机构】 合肥工业大学材料学院中国科学院固体物理研究所纳米技术中心中国科学院固体物理研究所纳米技术中心 合肥230009 中国科学院固体物理研究所纳米技术中心合肥230031合肥230031

【摘要】 在γ-Al2O3粉体中添加氧化铝胶体,研究其对氧化铝α相变的影响.结果表明,与α氧化铝粉体籽晶相比较,氧化铝胶体也可以起到籽晶的作用;由于其颗粒较小、在γ-Al2O3中分散均匀且能与之紧密接触,大大降低了α相变温度,改善了煅烧产物的微结构,从而得到分散均匀、平均粒径<100nm 的α氧化铝超细粉体,根据对粉体形貌 TEM 的观察,初步探讨了添加氧化铝胶体的前驱体α相变的过程。

【Abstract】 The effect of alumina sol on the α phase transformation in γ-alumina powder has been studied.Incomparison with α-alumina seeds,the alumina sol can also act as seeds.Moreover,because of the small particlesize and perfect dispersibility of the alumina sol,the α phase transformation temperature is decreased and,meanwhile,the microstructure of the produced powders is modified.So ultrafined powders with a particle sizeless than 100 nm were produced with good dispersibility.The α phase transformation of the alumina precursorswith alumina sol doping was studied on the base of the TEM photographs of the produced powders.

【关键词】 超细氧化铝溶胶籽晶α相变
【Key words】 UltrafinedAluminaSolSeedingα phase transformation
【基金】 安徽省自然科学基金(00046403)合肥工业大学中青年创新群体基金(103-037016)~~
  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,2005年01期
  • 【分类号】TB383
  • 【被引频次】25
  • 【下载频次】580
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