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磷酸锌中磷含量的快速测定
Rapid determination of phosphorus in zinc phosphate
【摘要】 采用磷钒钼黄比色法测定磷酸锌中磷含量。当磷含量为0 ~10mg/L时,直线方程线性关系良好,符合郎伯-比尔定律,吸光系数为1. 7×104 L/(mol·cm)。对比测定结果表明,磷钒钼黄比色法对实际样品测定结果与磷钼酸喹啉重量法相近,变异系数RSD<5. 00%,可作为磷酸锌产品磷的简洁、快速测定。
【Abstract】 Phosphorus content in zinc phosphate is determined by phosphorus vanadium molybdate yellow colorimetric method.The equation is linear and in accordant with Launber.Bill Law when the P content between 0 and 10 mg/L and the molar absorptivity is 1.7×10~4 L/(mol·cm).Comparison results show that the measured value by this method is close to that by phospho-molybdic quinoline gravimetric method .So it can be used as a convinient,fast and suitable method for the determination of phosphorus in zinc phosphate because of its RSD <5.00%.
【关键词】 分光光度法;
磷;
磷钒钼黄;
磷酸锌;
【Key words】 spectrophotometry; phosphourus; phosphorus vanadium molybdate yellow; zinc phosphate;
【Key words】 spectrophotometry; phosphourus; phosphorus vanadium molybdate yellow; zinc phosphate;
【基金】 广西科技厅青年基金项目(桂科青 0339012)。
- 【文献出处】 无机盐工业 ,Inorganic Chemicals Industry , 编辑部邮箱 ,2005年05期
- 【分类号】O657.32
- 【被引频次】1
- 【下载频次】199