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翁泉沟硼铁矿的综合利用

The comprehensive utilization of ascharite-magnetite mixed mineral at wengquan′gou

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【作者】 吕秉玲;

【Author】 Lü Bingling(School of chemical Engineering,Dalian University of Technology,Liaoning Dalian 116012,China)

【机构】 大连理工大学 辽宁大连116021;

【摘要】 提出了翁泉沟硼铁矿的综合利用流程:即矿石先经选矿而得硼精矿和硼铁混合精矿;硼精矿用碳碱法加工而得硼砂;硼铁混合精矿用硫酸溶解其中的硼镁石,在阻溶剂的作用下,磁铁矿溶解很少,酸解后进行固液分离,固相即为铁精矿,送去炼铁,酸解液除铁后,加入盐析剂氯化镁,在高温下蒸发析出硫酸镁,过滤后母液冷却至常温又析出硼酸,硼酸母液循环回到蒸发器,从而高回收率得到硫酸镁和硼酸。

【Abstract】 A Comprehensive utilization scheme for the ascharite-magnetite syngenetic mineral at Wengquan′gou have been laid out.By dressing,the ascharite concentrate and the ascharite-magnetite mixed concentrate are derived.The former is treated by soda-carbonation process to produce borax.The latter is treated by sulfuric acid to digest its ascharite content.In the presence of the retardant.only a very small portion of magnetite content is degested.After filtration,the solid cake being magnetite concentrate is sent to iron-smelting.The liquid phase after the removal of Fe2+ along with the salting-out agent MgCl2 is evaporated at higher temperature to crystallize MgSO4·H2O,After filtration of MgSO4·H2O,the mother liquor is cooled down to crystallize H3BO3,The mother liquor is recycled to the evaporator,thus the higher recovery efficiency of H3BO3 and MgSO4 might be achieved.

【关键词】 硼; 硼铁矿; 硼酸盐; 硫酸镁; 硼酸;
【Key words】 boron; borate; magnesium sulfate;
  • 【文献出处】 无机盐工业 ,Inorganic Chemicals Industry , 编辑部邮箱 ,2005年04期
  • 【分类号】TF521.6
  • 【被引频次】20
  • 【下载频次】302
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