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镧石型碳酸钕的形成及晶种对结晶的促进作用

Crystalline Neodymium Carbonate with Lanthanide Structure: Preparation, and Promoting Action of Seeding on Crystallization

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【作者】 丁家文李永绣黄婷罗贤满杨毅何小彬

【Author】 DING Jia-Wen LI Yong-Xiu* HUANG Ting LUO Xian-Man YANG Yi HE Xiao-Bin (Research Center for Rare Earths & Micro/Nano Functional Materials, Nanchang University, Nanchang 330047)

【机构】 南昌大学稀土与微纳功能材料研究中心南昌大学稀土与微纳功能材料研究中心 南昌330047南昌330047南昌330047

【Abstract】 The characteristics of pH value variation during aging process of amorphous neodymium carbonate formed by three different feeding manners have been investigated. The promotion action of seeding on the crystallization of neodymium carbonate is discussed. X-ray diffraction pattern and the elemental analysis results show that neodymium carbonate can transfer from amorphous to crystalline normal neodymium carbonate Nd2(CO3)3·8H2O with lanthanide structure at room temperature. Its crystallization activity zone lies in lower feeding ratio area expressed by n/n between 2~3. The existing of seeds can shorten crystalline time, from more than 15 h without seed to 2 h with seeds under normal feeding manner. And the spontaneity nucleation time can be shortened further when feeding with multi-steps normal manner. However, whether multi-steps normal or synchronously and continuously feeding manner, the precipitate formed can transfer to crystalline neodymium carbonate directly under seeding. At the same time, it is observed that the variation of pH value reduces with the decrease of feeding amount and the shortening of aging period, indicating that with synchronously and continuously feeding manner can not only realize fast crystallization, but also control pH value within a narrow range, which is beneficial for the producing of neodymium carbonate crystal with narrow-distributed particle size and monitoring of its crystallization process.

【基金】 国家自然科学基金(No.59764001);江西省自然科学基金(No.Q97001)资助项目。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2005年08期
  • 【分类号】O614.335
  • 【被引频次】26
  • 【下载频次】249
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