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棒状钡铁氧体的反相微乳法制备

Preparation of Rodlike Barium Ferrite Particles by Inverse Microemulsion Method

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【作者】 杨鹏飞王明刚孟凡君张俊华孙爱娟鲁成学

【Author】 YANG Peng-Fei WANG Ming-Gang MENG Fan-Jun* ZHANG Jun-Hua SUN Ai-Juan LU Cheng-Xue(School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100)

【机构】 山东大学化学与化工学院山东大学化学与化工学院 济南250100济南250100济南250100

【Abstract】 A rodlike barium ferrite precursor with an average size of 0.72~19.6 μm and aspect ratio of 2.6~8.3 has been successfully prepared in an inverse microemulsion consisting of isooctane, cetanyl trimethyl ammonium bromide (CTAB), n-C4H9OH and water with ammonia and ammonium oxalate as precipitants. On sintering at 780(C, the rodlike precursor particles could be transformed into rodlike particles of barium ferrite(BaFe12O19) with the average size and aspect ratio of 0.69~18.2 μm and 2.3~5.8, respectively. The effect of volume ratio of aqueous phase to oleic phase, the starting concentrations of metal ions and the starting concentration ratios of metal ions to precipitants were investigated.

【基金】 山东省优秀中青年科学家基金资助项目(No.2004BS04015)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2005年04期
  • 【分类号】TQ584.1
  • 【被引频次】29
  • 【下载频次】269
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