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金（Ⅲ）与杯[4]乙酯合钠髣超分子化合物:[Na(C60H80O12)]+[Au（SCN）4]-的合成、结构及性能
Synthesis,Crystal Structure and Characterization ofa Novel Super Molecule [Na(C60H80O12)]+[Au（SCN）4]-
【Abstract】 A novel super molecule [Na(C60H80O12)]+- was obtained by ext raction of calix arene (L) for an aqueous solution containing -, and N aCl into CH2Cl2. The crystal structure and properties of the title super molecul e were characterized by single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragon al system with space group P4/n and the unit cell parameters were as follows: a= 2.880 8(18) nm, b=2.880 8(18) nm, c=2.292 4(5) nm, and final R indices : R1=0.048 5, wR2=0.106 1. CCDC: 243229.
【关键词】 杯[4]芳烃；
金髥；
超分子化合物；
合成；
晶体结构；
【Key words】 calixarene； gold(III)； association complex； synthesis； crystal str ucture；
【Key words】 calixarene； gold(III)； association complex； synthesis； crystal str ucture；
【基金】 国家自然科学基金资助项目(No.20171040);郑州大学青年骨干教师基金资助项目
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2005年03期
- 【分类号】O627.1
- 【下载频次】92