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双取代单酰胺与硝酸铀酰萃合物的制备与表征

Preparation and Characterization of Extracted Species of Uranyl Nitrate with Disubstituted Monoamides

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【作者】 孙国新于涛崔玉张振伟李业新

【Author】 SUN Guo-Xin* YU Tao CUI Yu ZHANG Zhen-Wei LI Ye-Xin(Institute of Chemistry and Chemical Engineering, Jinan University, Jinan 250022 )

【机构】 济南大学化学化工学院济南大学化学化工学院 济南250022济南250022济南250022

【摘要】 合成了系列双取代单酰胺萃取剂,利用萃取方法获得了与硝酸铀酰的萃合物。利用元素分析、红外光谱、1HNMR和13CNMR对萃合物进行了表征。结合实验数据初步探讨了萃合物的结构、萃取剂的结构与性能以及萃取体系的三相等问题。

【Abstract】 A series of disubstituted monoamides extractants were synthesized and their extracted species with uranyl nitrate were obtained by extraction method. The foregoing extracted species were characterized by elemental analysis, infrar ed spectra, 1H NMR and 13C NMR. The structure of the extracted species, the rela tionship between extractant structure and extractability, and also the third pha se formed in the extraction systems were discussed primarily based on the experi mental data.

【关键词】 单酰胺硝酸铀酰萃合物结构表征
【Key words】 monoamideuranyl nitrateextracted speciesstructurecharaterizat ion
【基金】 国家自然科学基金(No.20301008);山东省自然科学基金(No.Q2003B01)资助项目
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2005年03期
  • 【分类号】TQ413
  • 【被引频次】2
  • 【下载频次】117
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