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胶束溶液中钴(Ⅲ)配合物催化磷酸二酯水解的研究
CATALYTIC HYDROLYSIS OF PHOSPHATE DIESTER BY Co(Ⅲ) COMPLEX IN MICELLAR SOLUTION
【摘要】 研究了在30℃二水(四胺类)合钴(Ⅲ)配合物在表面活剂Brij35胶束溶液中的增溶和催化二(对硝基苯酚)磷酸二酯的水解,暗示着顺式二水高价金属离子配合物形成金属胶束是一个潜在的磷酸二酯水解剪切的催化剂。
【Abstract】 The solubilization of diaquo(tetramine-base)Cobalt(Ⅲ) complex in Brij35 micellar solution and its catalytic hydrolysis of bis(p-nitrophenyl) phosphate diester were investigated at 30℃. The results indicate that the cis- diaquo metal ions with high valence complex in micellar solution is a potential catalyst for the hydrolytic cleavage of phosphate diester.
- 【文献出处】 武汉工业学院学报 ,Journal of Wuhan Polytechnic University , 编辑部邮箱 ,2005年02期
- 【分类号】O643.32
- 【被引频次】1
- 【下载频次】75