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氧化镧改性沸石除磷脱氮研究

Nitrogen and Phosphate Removal by Activated Zeolite with Lanthana

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【作者】 李彬宁平陈玉保邓春玲江喆

【Author】 LI Bin, NING Ping, CHEN Yu-bao, DENG Chun-ling, JIANG Zhe(School of Environmental Science and Technology, Kunming University of Science and Technology, Kunming 650093,China)

【机构】 昆明理工大学环境科学与工程学院昆明理工大学环境科学与工程学院 昆明650093昆明650093昆明650093

【摘要】 在镧离子质量浓度0.5%,pH为10下浸渍16 h以上,于110℃干燥陈化24 h后,再于450~500℃焙烧1 h,冷却后过筛取筛下粒径120目以上为最佳稀土吸附剂,用于静态同步脱氮除磷试验。结果表明,对正磷和氨氮的进水最佳pH为4,此时最大静态吸附分别达到25 mg/g和50 mg/g;当进水pH为4~8,氨氮浓度为10 mg/L,正磷浓度5 mg/L时,出水pH在6~9之间,对二者的去除效率分别达到80%和99%,吸附剂再生7次后对氮磷的去除率仍然保持在80%以上,动力学符合Freundlich吸附模型,相关系数在0.99以上。为处理微污染的氮磷提供了一条新的途径。

【Abstract】 Adsorbent was firstly immersed in solution of La3+ with concentration of 0.5% and pH of 10 for more than 16 h; secondly it was dried up and stabilized at temperature of 110 ℃ for 24 h; then it was roasted at temperature between 400~(500 ℃) for 1 h; finally that with radius more than 120 mesh was chosen to remove ammonia nitrogen and phosphate synchronously in static experiment. According to this experiment, optimal pH was 4 and the largest static adsorbing capacities for NH+4-N and H2PO-4 were 25 mg/g and (50 mg/g) respectively. In influence of NH+4-N and H2PO-4 with concentrations of 10 mg/L and (5 mg/L) respectively, following results can be identified: removal efficiencies can reach 80% and 90% respectively; Removal efficiencies were still more than 80% after being regenerated for 7 times; Dynamics for this process was in accordance with Freundlich adsorption model with a correlation efficient of more than 0.99. This experiment provided a new way for treatment of NH+4-N and H2PO-4 in slightly polluted water.

【基金】 云南省自然科学基金(2000B0023M).
  • 【文献出处】 武汉理工大学学报 ,Journal of Wuhan University of Technology , 编辑部邮箱 ,2005年09期
  • 【分类号】X703
  • 【被引频次】85
  • 【下载频次】973
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