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BaO和Li2O对CaO基脱硫精炼渣熔点和粘度的影响
Effect of BaO and Li2O on Melting Point and Viscosity of CaO-Based Refining Fluxes for Desulphuration
【摘要】 以CaO(bal)-SiO2(22.4%)-Al2O3(11.6%)-CaF2(10%)精炼渣作为基础渣系,用BaO、Li2O替代其中等量的CaO含量,固定(CaO+RxO)/SiO2=2.5(RxO代表BaO或者Li2O),对该脱硫精炼渣系的熔点和粘度进行了研究。结果显示在传统的CaO基熔渣中加入BaO、Li2O可以降低渣系的熔点和粘度,有效地改善了渣钢反应的动力学条件。当(BaO,Li2O)=15%时,熔渣的熔点分别为1267℃和1185℃,远低于不加添加剂时的熔点1326℃,当温度为1475℃时,熔渣粘度分别为0.98Pa·s和0.51Pa·s,远小于不加添加剂时的粘度1.79Pa·s,使渣系具有良好的流动性和熔化性能。
【Abstract】 The melting point and viscosity of refining fluxes for desulphuration have been studied, of which CaO (balance)-SiO2(22.4%)-Al2O3(11.6%)-CaF2(10%) refining slag was as basic flux, when the ratio of (CaO+RxO)/SiO2 was fixed at 2.5 (where RxO- BaO or Li2O), the BaO or Li2O added and replaced equivalent CaO content in flux. The results showed that the melting point and viscosity of fluxes decreased by added BaO or Li2O in CaO basic slag effectively to improve the dynamics condition of metal- slag reaction. With 15%BaO or 15%Li2O, the melting point of flux was (1 267) ℃ or (1 185) ℃ which were far lower than that of flux free additions- 1326 ℃, and the viscosity of flux at (1 475) ℃ was 0.98 Pa·s or 0.51 Pa·s which were also far lower than that of flux free additions- 1.79 Pa·s to make the fluxes had excellent fluidity and melting capacity.
- 【文献出处】 特殊钢 ,Special Steel , 编辑部邮箱 ,2005年04期
- 【分类号】TF769
- 【被引频次】19
- 【下载频次】334