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异辛醇磷酸酯的合成及在渗花工艺中的应用

The Preparation and Application in Pe netrating Glaze of n-octanol Phosphoric Ester

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【作者】 杨海波林营乔永洛

【Author】 Yang Haibo,Lin Ying,Qiao Yongluo(School of Material Science and E ngineering ,Shaanxi University of S cience and Technology,Xianyang,712081)

【机构】 陕西科技大学材料科学与工程学院陕西科技大学材料科学与工程学院 咸阳712081咸阳712081咸阳712081

【摘要】 以异辛醇和五氧化二磷为原料,分析了各种试验条件对合成反应的影响,结合反应转化率和产物渗透性分析,得出了最佳合成工艺条件为n(异辛醇 )∶n(五氧化二磷) =(2~3 )∶1,酯化时间3h ,酯化温度70℃。并讨论了异辛醇磷酸酯渗透剂在渗花生产工艺中的应用性能。

【Abstract】 Ethyl hexanol phosphoric ester was prepared with 2-Ethyl hexanol and di-phospphorus p entoxide.Main experiment factors affecting the reaction were discussed and with composite analysis of the product and with the reaction conversion optimum techn ological conditions were given:Molar ratio of 2-Ethyl hexanol to di-phosphorus pentoxide was (2~3)∶1,esterification time was about 3?h,and reaction temperat ure was controlled at 70?℃.And its application in penetrating glaze was introd uced.

【基金】 国家自然科学基金项目资助,项目编号 50 372 0 37
  • 【分类号】TQ174.6
  • 【被引频次】3
  • 【下载频次】314
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