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氢化物发生-原子荧光光度法测定水和废水中铅的实验研究

Experimental Research on Determination of Lead in Water and Wasted Water by Hydride Generation-Atomic Fluorescence Method

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【作者】 张延刘光学

【Author】 ZHANG Yan1,2, LIU Guang-xue3(1.Anhui University, Hefei 230039, China; 2.Anhui Water Environmental Monitoring Center, Hefei 230022, China;3.Tianjin Water Environmental Monitoring Center, Tianjin 300060, China)

【机构】 安徽大学化学系天津市水环境监测中心 安徽合肥230039 安徽省水环境监测中心安徽合肥230022天津300060

【摘要】 对测定水和废水中铅含量的氢化物发生-原子荧光光度法进行了实验研究,该方法具有灵敏度高、干扰少、操作简便等优点,优化了测定水和废水中铅的条件,对Fe3+、Mn2+、Ni2+、Hg2+、Zn2+、Cr6+、Cu2+、Cd2+等金属离子的干扰情况进行了实验,并对高、中、低浓度的标准物质和废污水进行了一系列测定,实验结果令人满意。

【Abstract】 A method is reported for determination of lead in water and wasted water by hydride generation-atomic fluorescence method. The best condition for the determination and the interference from coexistent elements such as Fe3+, Mn2+, Ni2+, Hg2+, Zn2+, Cr6+, Cu2+ and Cd2+ in water are studied. In the given conditions, the detecting limit is 0.76μg/L, the recovery rate of the known sample is 95.1%~108% and the relative standard deviation is less than 5%. The result is satisfying.

  • 【分类号】O661.1;X832
  • 【被引频次】6
  • 【下载频次】196
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