【摘要】 在水溶液中以对苯二甲酸根(TPHA)为桥联配体,端接1,10-邻菲罗啉(phen)合成了一个新的三元混配的配合物[Cu2(TPHA)(phen)4].2ClO4,经元素分析以及红外光谱等手段,推定该配合物具有TPHA桥联双核铜(Ⅱ)结构,铜(Ⅱ)离子处于五配位的四角锥环境.更多还原

【Abstract】 A new terephthalato-bridged binuclear copper（II） complex with the formula [Cu₂（TPHA）（phen）₄·2ClO₄,where phen stands for 1,10-phenanthroline and TPHA respresents the terephthalate dianions,has been synthesized and characterized.Based on IR and elemental analyses,the complex is proposed to have extened TPHA-bridged structure consisting of two copper（II）ions in which each copper（Ⅱ）ion has square pyramidal environment with five-coordinated.更多还原