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添加BaO和Li2O对CaO基脱硫精炼渣熔点和粘度的影响

EFFECT OF BaO AND Li2O ON MELTING POINT AND VISCOSITY OF CaO-BASED FLUXES

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【作者】 祝贞学; 戴起勋; 李桂荣; 王宏明; 徐明喜;

【Author】 Zhu Zhenxue Dai Qixun Li Guirong Wang Hongming Xu Mingxi(School of Materials Science and Engineering, Jiangsu University)

【机构】 江苏大学材料科学与工程学院; 江苏大学材料科学与工程学院 江苏镇江212013; 江苏镇江212013; 江苏镇江212013;

【摘要】 以CaO-SiO2(22·4%)-Al2O3(11·6%)-CaF2(10%)精炼渣作为基础渣系,添加BaO或Li2O,固定(CaO+BaO或Li2O)/SiO2=2·5,研究渣系熔点和粘度等熔体特性的变化。结果显示加入BaO、Li2O可以明显降低渣系的熔点和粘度,有效改善渣钢反应的动力学条件。当(BaO,Li2O)=15wt%时,熔渣的熔点分别为1267℃和1185℃,远低于作对比的基础渣的熔点1326℃,当温度为1475℃时,熔渣粘度分别为0·98Pa·s和0·51Pa·s,远小于基础渣的粘度1·79Pa·s,使渣系具有良好的流动性,将显著提高炼钢精炼渣的精炼性能。

【Abstract】 A refining slag of CaO( bal) -SiO2( 22.4%) -Al2O3( 11.6%) -CaF2( 10%) was selected as the basic slags. The effect of additives (BaO or Li2O) on melting point and viscosity of CaO-based slags was studied when the ratio of (CaO+BaO or Li2O) /SiO2 was fixed at 2.5. The results showed that the melting point and viscosity of slags decreased by adding BaO or Li2O into CaO-based slags, the dynamics condition of metal slags reaction was improved effectively. When (Li2O or BaO) =15%, the melting point (1185℃,1267℃) of slags were much lower than that (1326℃) of slag without additives, the viscosity(0.51Pa·s, 0.98 Pa·s)of slag at 1475℃ was much lower than that (1.79 Pa·s) of slag without additives. The fluidity of slags was good enough to satisfy the requirement of the melting capacity of fluxes.

【关键词】 CaO基熔渣; BaO; Li2O; 熔点; 粘度;
【Key words】 CaO-based Flux; BaO; Li2O; Melting Point; Viscosity;
【基金】 国家自然科学基金项目(50474037);江苏省高校自然科学研究项目(04BJK430022)
  • 【分类号】TF769
  • 【被引频次】7
  • 【下载频次】261
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