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阿利特-硫铝酸钡钙水泥熟料矿相体系的组成结构与性能

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【摘要】 研究了以阿利特-硫铝酸钡钙为主导矿物的熟料矿相体系C3S-C2.75B1.25A3S-C2S-C2F,探讨了该体系的组成与匹配关系。研究结果表明,阿利特、硫铝酸钡钙这两种高低温型矿物可以在1380℃煅烧条件下共存于同一熟料中。从该矿相体系的力学性能分析可知,熟料的最佳质量分数C2.75B1.25A3S为55%,C3S为15%,C2F为5%,C2S为25%。在该组成条件下,熟料的1d和3d抗压强度均在40MPa以上,展现了良好的快硬早强性能。影响熟料1d、3d强度的主要因素是C3S和C2.75B1.25A3S矿物的含量,影响28d强度的主要因素是C3S和C2F含量。同时,利用SEM-EDS和XRD分析了熟料的组成与结构。

【Abstract】 Composition,Structure and Performance of Alite-calcium Barium Sulphoaluminate Clinker System$$$$ LU Ling-chao1,2 ,SHEN Ye-qing2,CHANG Jun2,CHENG Xin2,LIU Han-xing1,YUAN Run-zhang1(1.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China;2.School of Material Science and Engineering,Jinan University,Jinan 250022,China) Abstract:A mineral system with C3S-C<sup>2.75 B<sup>1.25 A3S-C2S-C2F is synthesized and its dominant minerals are Alite (C3S) and calcium barium sulphoaluminate (C<sup>2.75 B<sup>1.25 A3S).The relationships between the composition,structure and performances for the system are researched.The experiments show Alite and C<sup>2.75 B<sup>1.25 A3 S can coexist in a clinker system burnt at 1?380?℃.The main influencing factors on 1?d,3?d and 28?d strength of the clinker are the content of C3S,C<sup>2.75 B<sup>1.25 A3S and C3S,C2F individually.The optimum constituent of the clinker system is C<sup>2.75 B<sup>1.25 A3S 55%,C3S 15%,C2F 5% and C2S 25%.Under the condition of the optimum level,the compressive strength of the clinker at 1?d,3?d curing age exceed 40?MPa individually.Accordingly,the clinker system has an excellent performance of high-early strength.The constituent and structure of the clinker system are analyzed with the help of SEM-EDS and XRD. Keywords:materials science;C3S;C2.75B1.25A3;mineral system;early strength

【关键词】 材料学C3SC2.75B1.25A3矿相体系早期强度
【基金】 国家973计划资助项目(2001CB610701);山东省自然科学基金资助项目(Y2003F02)
  • 【文献出处】 济南大学学报(自然科学版) ,Journal of Jinan Uniuersity , 编辑部邮箱 ,2005年02期
  • 【分类号】TQ172.2
  • 【被引频次】7
  • 【下载频次】126
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