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新型催化材料——SAPO分子筛
Novel Catalytic Material:SAPO Molecular Sieves
【摘要】 磷酸硅铝分子筛(SAPO)是由SiO2、AlO2-、PO2+三种四面体单元构成的微孔型晶体,具有从六元环至十二元环的孔道结构,孔径在0.3mm~0.8mm,骨架呈负电性,具有可交换的阳离子,被广泛用作吸附剂、催化剂和催化剂载体,是一种具有优异择形选择性、热稳定性和湿热稳定性的新型催化材料。SAPO分子筛可呈现出由中强酸到强酸的催化性能,几乎可用于所有的烃类反应。
【Abstract】 Silicon aluminum phosphate (SAPO) molecular sieves are microporous crystals with the structure of SiO2AlO-2PO+2 tetrahedral units. SAPO have electronegative framework and exchangeable cation and Lewis acidity. SAPO is a novel class of catalytic materials which exhibit excellent shape selectivity, thermal stability and hydrothermal stability,which can catalyze hydrocarbon reactions.
【关键词】 SAPO;
催化材料;
择形选择性;
热稳定性;
湿热稳定性;
【Key words】 <Keyword>SAPO; catalytic material; shape selectivity; thermal stability; hydrothermal stability;
【Key words】 <Keyword>SAPO; catalytic material; shape selectivity; thermal stability; hydrothermal stability;
- 【文献出处】 山西化工 ,Shanxi Chemical Industry , 编辑部邮箱 ,2005年03期
- 【分类号】TQ426
- 【被引频次】23
- 【下载频次】651