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碳气凝胶电极用于NaCl溶液电容性除盐的研究
APPLICATION OF CARBON AEROGELS ELECTRODES TO CAPACITIVE DEIONIZATION OF NACL SOLUTIONS
【摘要】 碳气凝胶是一种新型多孔碳材料,具有比表面积大、电导率高的特点。本文通过常压干燥制备了碳气凝胶,研究测试了其结构特性,用N aCl溶液模拟海水,利用CD I原理,以碳气凝胶作电极进行了N aC l溶液的除盐实验。实验表明,决定碳气凝胶的除盐效果的主要因素为比表面积和电导率。在不同配比结构中,以R/C为1500、M值为30%的碳气凝胶电极的除盐效果最佳。利用双电层电容模型解释探讨了碳气凝胶电极的除盐机理。
【Abstract】 Carbon aerogels are a kind of new porous carbon materials and have high specific surface area and conductance. In this paper, carbon aerogels are obtained through ordinary pressure drying; their structural properties are investigated. Carbon aerogels are used as the electrode material to desalinate the NaCl solutions instead of the simulative seawater by capacitive deionization principle. It is shown that the desalinated efficiency is mainly decided by specific surface area and conductance. The sample with R/C being 1500 and M being 30% is the best one of all the carbon earogels in desalination. The mechanism of desalination is discussed with the model of electronic double-layer capacitor.
【Key words】 carbon aerogels; seawater desalination; capacitive deionization;
- 【文献出处】 水处理技术 ,Technology of Water Treatment , 编辑部邮箱 ,2005年04期
- 【分类号】TQ427.6
- 【被引频次】50
- 【下载频次】496