【摘要】 纳米粒子由于具有大量的潜在应用,近年来已引起人们极大的关注.通过纳米复合技术(如制备核壳结构的纳米粒子)可以使其获得更多的特殊性质.以氢氧化钡、氢氧化锶、钛酸丁酯为主要原料,采用化学溶液法,在80℃左右的温度下制备了钛酸锶钡纳米晶.硝酸镁和硝酸锌的混合溶液同钛酸锶钡混合并超声搅拌,在室温下制备了具有核壳结构的(Ba,Sr)Ti O3/MgxZn1-xO(BST/MZO)纳米晶.x射线衍射(xRD)和场发射扫描电子显微镜(FESEM)确定所制备样品为纯钙钛矿结构,透射电镜(TEM)表明产品的形貌是核壳结构小球,电子衍射图案进一步证实核和壳均是由十几个到几十个纳米的(Ba,Sr)Ti O3/MgxZn1-xO纳米晶组成的聚集体.采用常规的陶瓷制备技术获得具有核壳结构复合陶瓷,其介电性能明显改善.研究结果表明具有核壳结构的(Ba,Sr)Ti O3/MgxZn1-xO适合作为微波介电材料.更多还原

【Abstract】 BST nanoparticles were directly synthesized from solution at 80℃ and then wrapped with zinc doped MgO in solution under ultrasonic dispersion at room temperature.This core-shell structure was analyzed by a conjunction of XRD, HRTEM and FE-SEM. The lattice cell parameter of BST core was found to have shrinkage. The lattice cell mismatch between core and shell make a fluctuation of lattice cell parameter of BST core. The nanoparticles can also be observed by FESEM in fractured grains of the ceramics. The dielectric properties were evaluated at different temperatures and frequencies. It is obvious that the core-shell structured BST composites are promising candidates to be used in high frequency devices.更多还原