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碘甲磺隆钠盐的水解特性

Characterizing Hydrolysis of Iodosulfuron-Sodium

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【作者】 唐美珍; 郭正元; 袁敏; 杨仁斌;

【Author】 TANG Mei-Zhen, GUO Zheng-Yuan, YUAN Min, YANG Ren-Bin (Institute of Agro-Environmental Protection, Hunan Agricultural University, Changsha 410128, China)

【机构】 湖南农业大学农业环境保护研究所; 湖南农业大学农业环境保护研究所 长沙410128; 长沙410128; 长沙410128;

【摘要】 通过实验室的模拟试验研究了碘甲磺隆钠盐在不同温度、pH值及不同水体条件下的水解动态。结果表明:碘甲磺隆钠盐在正常的环境条件(水的pH值为7,25℃,灭菌)下,碘甲磺隆钠盐难以水解,其降解半衰期长达157.5d,而在酸性条件下稳定性较差,容易水解,其半衰期缩短了10倍,仅为15.5d;温度对碘甲磺隆钠盐的水解速率有一定的影响,当pH为4时,其水解速率随温度的升高而加快,当温度为15℃、25℃、35℃时,半衰期分别为23.9、15.5、12.3d;碘甲磺隆钠盐在蒸馏水中的水解速率与在河水中的水解速率相似。

【Abstract】 The dynamics of iodosulfuron-sodium hydrolysis were studied in laboratory simulation experiments at different temperatures, pH, and water conditions. Iodosulfuron-sodium hydrolyzed with difficulty under normal environmental conditions (sterile water at pH 7 and 25℃), with a half-life of 157.5 days. Its stability was relatively low, however, in acidic conditions where it hydrolyzed readily, with a half-life of 15.5 days (only one-tenth as long). Iodosulfuron-sodium hydrolysis rates were affected somewhat by temperature. At pH 4, hydrolysis rate increased with increasing temperature, with half-lives of 23.9, 15.5, and 12.3 d at 15, 25, and 35℃, respectively. Iodosulfuron- sodium hydrolysis rates were similar in distilled and river water.

【关键词】 水解; 碘甲磺隆钠盐; 除草剂;
【Key words】 hydrolysis; iodosulfuron-sodium; herbicide;
【基金】 农业部下达的中法合作项目(NC20021406)
  • 【分类号】TQ450.2
  • 【被引频次】10
  • 【下载频次】92
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