【摘要】 合成了一个草酰胺桥联的异三核配合物,并解析了配合物的晶体结构,配合物处于正交晶系,空间群为Pbcn,a=1.424 2(7)nm,b=1.227 6(5)nm,c=3.464 8(15)nm,Z=8,R 1=0.079 1,wR 2=0.159 2.研究了配合物的红外光谱、电子光谱以及荧光光谱.对电子光谱进行了G auss ian分解,求出了相应的配体场参数.比较了配合物与金属盐的荧光强度,并对其进行了讨论.更多还原

【Abstract】 Oxamidato-bridged heterotrinuclear complex [Zn（CuL）₂N₃]-（ClO₄）·1.25 H₂O was been synthesized and characterized by IR、electronic spectra and fluorescence spectra. The crystal structure was determained. The complex crystallizes in the orthorhombic. Space group Pbcn, a=1.424 2（7） nm,b=1.227 6（5）nm, c=3.464 8（15） nm, Z=8,R1=0.097 1, wR2=0.159 2. The electronic spectra has been fitted by Gaussian and correlative coorination parameters have been obtained. The fluorescence spactra of title complex and Zn（ClO₄）₂ were campared and discussed.更多还原